Liquid K-Na Alloy Anode Enables Dendrite-Free Potassium Batteries

Adv Mater. 2016 Nov;28(43):9608-9612. doi: 10.1002/adma.201602633. Epub 2016 Sep 15.

Abstract

A K-Na liquid alloy allows a dendrite-free high-capacity anode; its immiscibility with an organic liquid electrolyte offers a liquid-liquid anode-electrolyte interface. Working with a sodiated Na2 MnFe(CN)6 cathode, the working cation becomes K+ to give a potassium battery of long cycle life with an acceptable capacity at high charge/discharge rates.

Keywords: alkali-metal batteries; dendrites; liquid alloys; potassium batteries.