Untargeted metabolomics analysis reveals dynamic changes in azelaic acid- and salicylic acid derivatives in LPS-treated Nicotiana tabacum cells

Biochem Biophys Res Commun. 2017 Jan 22;482(4):1498-1503. doi: 10.1016/j.bbrc.2016.12.063. Epub 2016 Dec 10.

Abstract

To counteract biotic stress factors, plants employ multilayered defense mechanisms responsive to pathogen-derived elicitor molecules, and regulated by different phytohormones and signaling molecules. Here, lipopolysaccharide (LPS), a microbe-associated molecular pattern (MAMP) molecule, was used to induce defense responses in Nicotiana tabacum cell suspensions. Intracellular metabolites were extracted with methanol and analyzed using a liquid chromatography-mass spectrometry (UHPLC-qTOF-MS/MS) platform. The generated data were processed and examined with multivariate and univariate statistical tools. The results show time-dependent dynamic changes and accumulation of glycosylated signaling molecules, specifically those of azelaic acid, salicylic acid and methyl-salicylate as contributors to the altered metabolomic state in LPS-treated cells.

Keywords: Azelaic acid; Innate immunity; Lipopolysaccharide; Metabolomics; Phytohormones; Salicylic acid.

MeSH terms

  • Biomarkers / chemistry
  • Chromatography, High Pressure Liquid
  • Chromatography, Liquid
  • Dicarboxylic Acids / chemistry*
  • Glycosylation
  • Lipopolysaccharides / chemistry*
  • Mass Spectrometry
  • Metabolomics
  • Multivariate Analysis
  • Nicotiana / chemistry*
  • Plant Growth Regulators / chemistry
  • Salicylic Acid / chemistry*
  • Spectrometry, Mass, Electrospray Ionization
  • Tandem Mass Spectrometry

Substances

  • Biomarkers
  • Dicarboxylic Acids
  • Lipopolysaccharides
  • Plant Growth Regulators
  • azelaic acid
  • Salicylic Acid