Iridium-catalysed hydrosilylation of cyclopropanes via regioselective carbon-carbon bond cleavage

Chem Commun (Camb). 2017 Aug 15;53(66):9281-9284. doi: 10.1039/c7cc04296e.

Abstract

While cyclopropanes have been explored as synthetically valuable building blocks, their transformation without conjugated substituents or directly substituted heteroatoms remains challenging. The current study describes the iridium-catalysed ring-opening hydrosilylation of cyclopropanes. A nitrogen-based directing group was found to control the reactivity of iridium active species as well as the regiochemistry of carbon-carbon bond cleavage and hydrosilylation.