Docking simulation between HIV peptidase inhibitors and Trypanosoma cruzi aspartyl peptidase

BMC Res Notes. 2018 Nov 21;11(1):825. doi: 10.1186/s13104-018-3927-z.

Abstract

Objective: The low investment in research, diagnosis and treatment are factors that contribute to the continuity of Chagas' disease as a neglected tropical diseases (NTDs). In this context, the repositioning of drugs represents a useful strategy, in the search for new chemotherapeutic approaches for NTDs. HIV aspartic peptidase inhibitors (HIV IPs) are good candidates for drug repurposing. Here, we modeled the three dimensional structure of an aspartyl peptidase of Trypanosoma cruzi, the causative agent of Chagas' disease, aligned it to the HIV aspartyl peptidase and performed docking binding assays with the HIV PIs.

Results: The 3D structure confirmed the presence of acid aspartic residues, which are critical to enzyme activity. The docking experiment revealed that HIV IPs bind to the active site of the enzyme, being ritonavir and lopinavir the ones with greater affinity. Benznidazole presented the worst binding affinity, this drug is currently used in Chagas' disease treatment and was included as negative control. These results together with previous data on the trypanocidal effect of the HIV PIs support the hypothesis that a T. cruzi aspartyl peptidase can be the intracellular target of these inhibitors. However, the direct demonstration of the inhibition of T. cruzi aspartyl peptidase activity by HIV PIs is still a goal to be persuaded.

Keywords: Aspartic peptidase; Chagas’ disease; Chemotherapy; Drug-repurposing; Neglected tropical diseases.

MeSH terms

  • Anti-HIV Agents / pharmacology*
  • Aspartic Acid Proteases / chemistry*
  • Atazanavir Sulfate / pharmacology
  • Crystallography, X-Ray
  • Databases, Protein
  • Drug Repositioning*
  • HIV / drug effects
  • Molecular Docking Simulation*
  • Nelfinavir / pharmacology
  • Peptide Hydrolases / chemistry*
  • Protease Inhibitors / pharmacology*
  • Protein Conformation
  • Saccharomyces cerevisiae Proteins / chemistry
  • Saquinavir / pharmacology
  • Trypanosoma cruzi / enzymology*

Substances

  • Anti-HIV Agents
  • DDI1 protein, S cerevisiae
  • Protease Inhibitors
  • Saccharomyces cerevisiae Proteins
  • Atazanavir Sulfate
  • Aspartic Acid Proteases
  • Peptide Hydrolases
  • Nelfinavir
  • Saquinavir