Selective Proteolysis to Study the Global Conformation and Regulatory Mechanisms of c-Src Kinase

ACS Chem Biol. 2019 Jul 19;14(7):1556-1563. doi: 10.1021/acschembio.9b00306. Epub 2019 Jul 9.

Abstract

Protein kinase pathways are traditionally mapped by monitoring downstream phosphorylation. Meanwhile, the noncatalytic functions of protein kinases remain under-appreciated as critical components of kinase signaling. c-Src is a protein kinase known to have noncatalytic signaling function important in healthy and disease cell signaling. Large conformational changes in the regulatory domains regulate c-Src's noncatalytic functions. Herein, we demonstrate that changes in the global conformation of c-Src can be monitored using a selective proteolysis methodology. Further, we use this methodology to investigate changes in the global conformation of several clinical and nonclinical mutations of c-Src. Significantly, we identify a novel activating mutation observed clinically, W121R, that can escape down-regulation mechanisms. Our methodology can be expanded to monitor the global conformation of other tyrosine kinases, including c-Abl, and represents an important tool toward the elucidation of the noncatalytic functions of protein kinases.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • CSK Tyrosine-Protein Kinase / chemistry*
  • CSK Tyrosine-Protein Kinase / genetics
  • CSK Tyrosine-Protein Kinase / metabolism
  • Humans
  • Models, Molecular
  • Neoplasms / enzymology
  • Neoplasms / genetics
  • Neoplasms / metabolism
  • Point Mutation
  • Protein Conformation
  • Proteolysis

Substances

  • CSK Tyrosine-Protein Kinase
  • CSK protein, human