Three new pterocarpans from the aerial parts of Abrus Precatorius

Nat Prod Res. 2020 Jul;34(13):1836-1844. doi: 10.1080/14786419.2018.1564293. Epub 2019 Jul 22.

Abstract

Three new pterocarpans, named abrusprecatins A-C (1-3), along with three known ones, namely medicarpin (4), maackiain (5), and 4-hydroxy-3-methoxy-8,9-methylenedioxypterocarpan (6) were isolated from the aerial parts of Abrus precatorius. The structures of these compounds were established by extensive analysis of mass spectrometric data, 1 D and 2 D NMR spectroscopic data. In addition, the absolute configurations were determined by a combination of single crystal X-ray diffraction analysis and circular dichroism spectroscopy.

Keywords: Abrus precatorius; abrusprecatins A-C; antibacterial activity; pterocarpans.

MeSH terms

  • Abrus / chemistry*
  • Crystallography, X-Ray
  • Molecular Conformation
  • Plant Components, Aerial / chemistry*
  • Pterocarpans / chemistry
  • Pterocarpans / isolation & purification*
  • Pterocarpans / pharmacology
  • Spectrum Analysis

Substances

  • Pterocarpans
  • medicarpin
  • inermin