Hybrid micelles containing methotrexate-conjugated polymer and co-loaded with microRNA-124 for rheumatoid arthritis therapy

Theranostics. 2019 Jul 9;9(18):5282-5297. doi: 10.7150/thno.32268. eCollection 2019.

Abstract

Purpose: Methotrexate (MTX) is a first-line drug for rheumatoid arthritis (RA)therapy. However, MTX monotherapy often results in irreversible joint damage due to its slow onset of action and long duration. microRNA-124 (miR-124) has shown direct bone protection activity against RA. A co-delivery system for MTX and microRNA combination may provide therapeutic synergy. Methods: Methotrexate-conjugated polymer hybrid micelles (M-PHMs) were prepared by self-assembly of two functional amphiphilic polymers (MTX-PEI-LA and mPEG-LA) at an optimized weight ratio. Incorporation of microRNA was achieved through electrostatic interactions between microRNA and cationic polymer MTX-PEI-LA. Cellular uptake, endosome escape, biodistribution, and therapeutic efficacy of M-PHMs/miR-124 complexes were investigated and evaluated in RAW264.7 cells and a rat adjuvant-induced arthritis (AIA) model. Results: M-PHMs/miR-124 complexes exhibited folate receptor-mediated uptake in activated RAW264.7 cells. miR-124 was able to escape from the endosome and down-regulate nuclear factor of activated T cells cytoplasmic1 (NFATc1). M-PHMs/miR-124 complexes accumulated in inflamed joints of AIA rats and showed superior therapeutic efficacy through both anti-inflammatory effect and direct bone protective effect. Combination of miR-124 and MTX in these micelles induced disease remission. Conclusions: M-PHMs/miR-124 was highly effective against RA through therapeutic synergy. Additional studies are warranted to further investigate its therapeutic potential and delineate its mechanisms of action.

Keywords: folate receptor; methotrexate; microRNA-124; polymeric hybrid micelles; rheumatoid arthritis.

MeSH terms

  • Animals
  • Arthritis, Rheumatoid / blood
  • Arthritis, Rheumatoid / drug therapy*
  • Cell Death / drug effects
  • Cytokines / blood
  • Disease Models, Animal
  • Endocytosis / drug effects
  • Endosomes / metabolism
  • Folate Receptor 1 / metabolism
  • Hemolysis / drug effects
  • Inflammation Mediators / blood
  • Joints / pathology
  • Linoleic Acid / chemical synthesis
  • Lipopolysaccharides
  • Methotrexate / pharmacology
  • Methotrexate / therapeutic use*
  • Mice
  • Micelles*
  • MicroRNAs / genetics
  • MicroRNAs / metabolism*
  • NFATC Transcription Factors / metabolism
  • Polyethylene Glycols / chemical synthesis
  • Polyethyleneimine / chemical synthesis
  • Polymers / chemistry*
  • Proton Magnetic Resonance Spectroscopy
  • RAW 264.7 Cells
  • Rats
  • Tissue Distribution / drug effects

Substances

  • Cytokines
  • Folate Receptor 1
  • Inflammation Mediators
  • Lipopolysaccharides
  • MIRN124 microRNA, rat
  • Micelles
  • MicroRNAs
  • NFATC Transcription Factors
  • Polymers
  • Polyethylene Glycols
  • Polyethyleneimine
  • monomethoxypolyethylene glycol
  • Linoleic Acid
  • Methotrexate