A sensitive in vitro performance assay reveals the in vivo drug release mechanisms of long-acting medroxyprogesterone acetate microparticles

Int J Pharm. 2020 Aug 30:586:119540. doi: 10.1016/j.ijpharm.2020.119540. Epub 2020 Jun 23.

Abstract

Today, a growing number of subcutaneously administered depot formulations enable continuous delivery of poorly soluble compounds over a longer time period. The modified liberation is considered to be a rate-limiting step in drug absorption and thus impacts therapeutic efficacy and product safety. In the present approach, a mechanism-based pharmacokinetic model of the commercial microparticle formulation depo-subQ provera 104™ (Sauter mean diameter of 5.08 ± 1.63 µm) was established. The model was verified using human pharmacokinetic data from three different clinical trials. Further, the effects of drug release, injection site and patient population on the pharmacokinetic profile were investigated. For this purpose, the drug release was assessed using the novel dispersion releaser technology, whereby a biorelevant medium reflecting major characteristics of the subcutaneous tissue (including ion background, buffer capacity and protein concentration) was used. The established model provided an effective prediction of the key pharmacokinetic parameters, including Cmax, Tmax and AUCall. Only in presence of 55% of fetal bovine serum (using a novel simulated subcutaneous interstitial fluid), the release assay was capable to discriminate between microparticles before and after storage.

Keywords: Biorelevant in vitro dissolution; Medroxyprogesterone acetate; Microparticle; PBPK modeling; Subcutaneous sustained release.

MeSH terms

  • Area Under Curve
  • Clinical Trials as Topic
  • Computer Simulation
  • Contraceptive Agents, Hormonal / administration & dosage*
  • Contraceptive Agents, Hormonal / pharmacokinetics
  • Delayed-Action Preparations
  • Drug Delivery Systems*
  • Drug Liberation
  • Humans
  • Medroxyprogesterone Acetate / administration & dosage*
  • Medroxyprogesterone Acetate / pharmacokinetics
  • Models, Biological*
  • Solubility
  • Technology, Pharmaceutical

Substances

  • Contraceptive Agents, Hormonal
  • Delayed-Action Preparations
  • Medroxyprogesterone Acetate