Rapid and sensitive quantification of cell-associated multi-walled carbon nanotubes

Nanoscale. 2020 Sep 7;12(33):17362-17372. doi: 10.1039/d0nr03330h. Epub 2020 Aug 13.

Abstract

Evaluating nanomaterial uptake and association by cells is relevant for in vitro studies related to safe-by-design approaches, nanomedicine or applications in photothermal therapy. However, standard analytical techniques are time-consuming, involve complex sample preparation or include labelling of the investigated sample system with e.g. fluorescent dyes. Here, we explore lock-in thermography to analyse and compare the association trends of epithelial cells, mesothelial cells, and macrophages exposed to gold nanoparticles and multi-walled carbon nanotubes over 24 h. The presence of nanomaterials in the cells was confirmed by dark field and transmission electron microscopy. The results obtained by lock-in thermography for gold nanoparticles were validated with inductively coupled plasma optical emission spectrometry; with data collected showing a good agreement between both techniques. Furthermore, we demonstrate the detection and quantification of carbon nanotube-cell association in a straightforward, non-destructive, and non-intrusive manner without the need to label the carbon nanotubes. Our results display the first approach in utilizing thermography to assess the carbon nanotube amount in cellular environments.

MeSH terms

  • Gold
  • Macrophages
  • Metal Nanoparticles*
  • Microscopy, Electron, Transmission
  • Nanotubes, Carbon*

Substances

  • Nanotubes, Carbon
  • Gold