A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction

Chem Commun (Camb). 2020 Nov 25;56(91):14179-14182. doi: 10.1039/d0cc05229a. Epub 2020 Oct 27.

Abstract

We report an unprecedented dinuclear catalyst for the electrochemical hydrogen evolution reaction (HER). A macrocyclic porphyrin complex comprising two nickel centres connected via redox mediating linker molecules gives rise to efficient catalysis, significantly outperforming a mononuclear reference catalyst.