Controlling the Structure of Carbon Deposit by Nitrogen Doping Catalytic Chemical Vapor Deposition Synthesis

J Nanosci Nanotechnol. 2021 Apr 1;21(4):2413-2418. doi: 10.1166/jnn.2021.18965.

Abstract

Nitrogen doped multi-walled carbon nanotubes and other carbon nanoparticles were synthesized by catalytic chemical vapor deposition of tripropylamine and acetylene on CaCO₃-supported cobalt catalyst (5 wt%), prepared by impregnation, and various precursors. Each synthesis was performed by using either the pure nitrogenous organic compound or its mixture with acetone. Transmission electron microscopy studies revealed a significant difference both in the yield and the diversity of the carbon deposits. Every synthesis resulted in bamboo-like nanotubes, and nearly all of them also in onion-like structures. Electron energy loss spectroscopy studies of the samples indicated the presence of nitrogen and calcium (caused by the catalyst support). High-resolution transmission electron microscopy and X-ray diffraction measurements were also performed to characterize the samples.

Publication types

  • Research Support, Non-U.S. Gov't