Antibody Conjugation of Fluorescent Nanodiamonds for Targeted Innate Immune Cell Activation

ACS Appl Nano Mater. 2021 Mar 26;4(3):3122-3139. doi: 10.1021/acsanm.1c00256. Epub 2021 Mar 11.

Abstract

Background: fluorescent nanodiamonds (FND) are nontoxic, infinitely photostable nanoparticles that emit near-infrared fluorescence and have a modifiable surface allowing for the generation of protein-FND conjugates. FND-mediated immune cell targeting may serve as a strategy to visualize immune cells and promote immune cell activation.

Methods: uncoated-FND (uFND) were fabricated, coated with glycidol (gFND), and conjugated with immunoglobulin G (IgG-gFND). In vitro studies were performed using a breast cancer/natural killer/monocyte co-culture system, and in vivo studies were performed using a breast cancer mouse model.

Results: in vitro studies demonstrated the targeted immune cell uptake of IgG-gFND, resulting in significant immune cell activation and no compromise in immune cell viability. IgG-gFND remained at the tumor site following intratumoral injection compared to uFND which migrated to the liver and kidneys.

Conclusion: antibody-conjugated FND may serve as immune drug delivery vehicles with "track and trace capabilities" to promote directed antitumor activity and minimize systemic toxicities.

Keywords: antibody conjugation; fluorescent nanodiamonds; immunotherapy; monocytes; natural killer cells.