Hyaluronic acid coated Pluronic F127/Pluronic P123 mixed micelle for targeted delivery of Paclitaxel and Curcumin

Int J Biol Macromol. 2021 Dec 1:192:950-957. doi: 10.1016/j.ijbiomac.2021.10.061. Epub 2021 Oct 15.

Abstract

The hydrophobicity of most of the anticancer drugs offers a great challenge in selecting a system for their effective transport. Here comes the importance of micelles that offers a hydrophobic core for incorporating these drugs. In this study, Hyaluronic Acid coated Pluronic mixed micelle loaded with Paclitaxel and Curcumin was designed and evaluated its anticancer activity in MCF-7 cells. Pluronic F127 (PF127) and Pluronic P123 (PP123) were taken for preparing the mixed micelles. The targeting ligand folic acid (FA) was conjugated to one end of PP123 forming FA-PP. The end hydroxyl groups of PF127 were oxidized to aldehyde groups resulted in PF-CHO. Mixed micelles were prepared from PF-CHO and FA-PP and the end aldehyde groups were used for coating the micelles with hyaluronic acid. The material was characterized using FTIR, H1NMR, DLS, FE-SEM and TEM. The coated micelles showed spherical shape with drug loading efficiency of 50.15 and 65.05% for Paclitaxel and Curcumin, respectively. In vitro drug release was studied at pH 5.5 and 7.4. Dual drug-loaded material showed higher in-vitro anticancer activity than free Paclitaxel and Curcumin. The results suggested that synthesized mixed micelle with dual drugs showed great potential for targeted delivery to MCF-7 cells.

Keywords: Hyaluronic acid and folic acid; Pluronic mixed micelles.

MeSH terms

  • Antineoplastic Agents / administration & dosage
  • Antineoplastic Agents / chemistry
  • Antineoplastic Agents / pharmacology
  • Apoptosis / drug effects
  • Cell Line, Tumor
  • Cell Survival / drug effects
  • Coated Materials, Biocompatible*
  • Curcumin / administration & dosage*
  • Curcumin / chemistry
  • Curcumin / pharmacology
  • Drug Carriers / chemistry*
  • Drug Compounding
  • Drug Delivery Systems
  • Humans
  • Hyaluronic Acid / chemistry*
  • Hydrophobic and Hydrophilic Interactions
  • Micelles*
  • Molecular Structure
  • Paclitaxel / administration & dosage*
  • Paclitaxel / chemistry
  • Paclitaxel / pharmacology
  • Particle Size
  • Poloxalene / chemistry*
  • Spectrum Analysis

Substances

  • Antineoplastic Agents
  • Coated Materials, Biocompatible
  • Drug Carriers
  • Micelles
  • pluronic block copolymer P123
  • Poloxalene
  • Hyaluronic Acid
  • Curcumin
  • Paclitaxel