The level of S-glutathionylated protein is a predictor for metastasis in colorectal cancer and correlated with those of Nrf2/Keap1 pathway

Biomarkers. 2021 Dec;26(8):780-787. doi: 10.1080/1354750X.2021.1999503.

Abstract

Introduction: The Nrf2 (nuclear factor erythroid 2-like 2; NFE2L2)/Keap1 (Kelch-like ECH-associated protein 1) pathway and the TXN (thioredoxin)/GSH (glutathione) system interact mutually and regulate cellular redox with impacts on cancer metastasis and S-glutathionylation of protein, which is an indicator of cell distress. This study investigates the levels of proteins in the Nrf2/Keap1 pathway and the TXN/GSH system and SGP (S-glutathionylated protein) in CRC (colorectal cancer) with or without metastasis.

Materials and methods: The protein levels of Nrf2, Keap1, Bach1 (BTB domain and CNC homolog 1), TXN, TXNRD1 (thioredoxin reductase 1), GSR (glutathione reductase) and SGP with molecular weight 31-172 kDa in the normal and tumour tissues of 64 CRC subjects were determined by Western blot.

Results: The protein levels and their T/N (tumour/normal tissue) ratios of the Nrf2/Keap1 pathway, the TXN/GSH system and SGP were correlated to different extents in the tissues of CRC subjects with or without lymph node/distant metastasis. The T/N ratios of SGP (odd ratio: 0.19; 95% CI: 0.04-0.74) and lympho-vascular invasion (4.2; 1.39-13.73) were significant predictors for metastasis.

Conclusions: SGPs have protein levels correlated with those of the Nrf2/Keap1 pathway and their T/N ratios are a negative predictor for metastasis in CRC.

Keywords: Colorectal cancer; Nrf2/Keap1 pathway; S-glutathionylated protein; TXN/GSH system; metastasis.

MeSH terms

  • Aged
  • Blotting, Western
  • Colorectal Neoplasms / metabolism*
  • Colorectal Neoplasms / pathology
  • Female
  • Glutathione / metabolism*
  • Humans
  • Kelch-Like ECH-Associated Protein 1 / metabolism*
  • Lymphatic Metastasis
  • Male
  • Middle Aged
  • NF-E2-Related Factor 2 / metabolism*
  • Neoplasm Metastasis
  • Prognosis
  • Protein Processing, Post-Translational
  • Proteins / metabolism*
  • Signal Transduction*
  • Thioredoxins / metabolism

Substances

  • KEAP1 protein, human
  • Kelch-Like ECH-Associated Protein 1
  • NF-E2-Related Factor 2
  • NFE2L2 protein, human
  • Proteins
  • TXN protein, human
  • Thioredoxins
  • Glutathione