Mollugin induced oxidative DNA damage via up-regulating ROS that caused cell cycle arrest in hepatoma cells

Chem Biol Interact. 2022 Feb 1:353:109805. doi: 10.1016/j.cbi.2022.109805. Epub 2022 Jan 8.

Abstract

Mollugin has been proven to have anti-tumor activity. However, its potential anti-tumor mechanism remains to be fully elaborated. Herein, we investigated the growth inhibition of HepG2 cells, as well as the anti-tumor effect of mollugin and its molecular mechanism on H22-tumor bearing mice. In vitro, mollugin was shown to have a strong inhibitory effect on HepG2 cells in a concentration-dependent manner. Mollugin induced S-phase arrest of HepG2 cells, and increased intracellular reactive oxygen species (ROS) levels. Comet assay demonstrated that mollugin induced DNA damage in HepG2 cells, as well as an increase in the expression of p-H2AX. In addition, mollugin induced changes in cyclin A2 and CDK2. However, the addition of antioxidant glutathione (GSH) was able to reverse the effect of mollugin. In vivo, mollugin significantly inhibited tumor growth and reduced the tendency of tumor volume growth in mice. The tumor cell density was found to be decreased in the administration group, and the content of ROS in the tumor tissue significantly increased. The expression of p-H2AX, cyclin A2 and CDK2 were consistent with in vitro results. Mollugin demonstrated anti-hepatocellular carcinoma activity in vitro and in vivo, and its anti-hepatocellular carcinoma activity was found to be related to DNA damage and cell cycle arrest induced by excessive ROS production in cells.

Keywords: Cell cycle arrest; DNA damage; Liver cancer; Mollugin; ROS.

MeSH terms

  • Animals
  • Antioxidants / chemistry
  • Carcinoma, Hepatocellular / drug therapy
  • Carcinoma, Hepatocellular / pathology
  • Cell Cycle Checkpoints / drug effects*
  • Cell Proliferation / drug effects
  • Cyclin A2 / genetics
  • Cyclin A2 / metabolism
  • Cyclin-Dependent Kinase 2 / genetics
  • Cyclin-Dependent Kinase 2 / metabolism
  • DNA Damage / drug effects
  • Hep G2 Cells
  • Humans
  • Liver Neoplasms / drug therapy
  • Liver Neoplasms / pathology
  • Male
  • Mice
  • Mice, Inbred BALB C
  • Oxidative Stress / drug effects*
  • Pyrans / chemistry
  • Pyrans / pharmacology*
  • Pyrans / therapeutic use
  • Reactive Oxygen Species / metabolism*
  • Up-Regulation / drug effects*

Substances

  • Antioxidants
  • Cyclin A2
  • Pyrans
  • Reactive Oxygen Species
  • rubimaillin
  • Cyclin-Dependent Kinase 2