Discovery of a new class of triazole based inhibitors of acetyl transferase KAT2A

J Enzyme Inhib Med Chem. 2022 Dec;37(1):1987-1994. doi: 10.1080/14756366.2022.2097447.

Abstract

We have recently developed a new synthetic methodology that provided both N-aryl-5-hydroxytriazoles and N-pyridine-4-alkyl triazoles. A selection of these products was carried through virtual screening towards targets that are contemporary and validated for drug discovery and development. This study determined a number of potential structure target dyads of which N-pyridinium-4-carboxylic-5-alkyl triazole displayed the highest score specificity towards KAT2A. Binding affinity tests of abovementioned triazole and related analogs towards KAT2A confirmed the predictions of the in-silico assay. Finally, we have run in vitro inhibition assays of selected triazoles towards KAT2A; the ensemble of binding and inhibition assays delivered pyridyl-triazoles carboxylates as the prototype of a new class of inhibitors of KAT2A.

Keywords: KAT2A inhibitors; N-pyridine triazoles; acetyl transferases; anti-cancer; virtual screening.

MeSH terms

  • Acetyltransferases*
  • Carboxylic Acids / chemistry
  • Molecular Structure
  • Structure-Activity Relationship
  • Triazoles* / chemistry
  • Triazoles* / pharmacology

Substances

  • Carboxylic Acids
  • Triazoles
  • Acetyltransferases

Grants and funding

This work was supported by Irish Research Council (GOIPG/2018/3165), Programma Operativo Nazionale Ricerca e Competitività (Ricerca e Innovazione 2014-2020 AIM), and VALERE (EPInhibitDRUGre (CUP B66J20000680005).