Tumor Selective Metabolic Reprogramming as a Prospective PD-L1 Depression Strategy to Reactivate Immunotherapy

Adv Mater. 2022 Oct;34(41):e2206121. doi: 10.1002/adma.202206121. Epub 2022 Sep 7.

Abstract

Currently, the role of the lysosome, endoplasmic reticulum, or dictyosome in the transcription and translation of programmed cell death ligand 1 (PD-L1) is well revealed, but the role and function of mitochondria in the PD-L1 expression in tumors is still not fully researched, making it hard to offer a novel PD-L1 regulation strategy. In this research, it is newly revealed that mitochondria oxidative phosphorylation (OXPHOS) depression can be used as an effective PD-L1 down-regulation method. To offer an ideal and high-effective tumor mitochondria-targeted OXPHOS depression nanosystem, IR-LND is prepared by conjugating mitochondria-targeted heptamethine cyanine dye IR-68 with mitochondrial complexes I and II depression agent lonidamine (LND), which then further self-assembled with albumin (Alb) to form IR-LND@Alb nanoparticles. By doing this, PD-L1 expression in tumors is selectively and effectively depressed by IR-LND@Alb nanoparticles. As expected, the anti-tumor efficacy of such a PD-L1 depression strategy is superior to conventional anti-PD-L1 monoclonal antibodies. Interestingly, IR-LND can also be served as a novel ideal promising photodynamic therapy (PDT) drug with self-oxygen and self-PD-L1 regulation capacity. All in all, this tumor-selective metabolic reprogramming platform to reactivate immunotherapy and sensitize for PDT effect, would open a new window for mitochondrial immunotherapy for cancer patients.

Keywords: immunotherapy; mitochondria; photodynamic therapy; programmed death ligand-1; tumor targeting.

MeSH terms

  • Albumins
  • Antibodies, Monoclonal
  • B7-H1 Antigen / metabolism
  • Carbocyanines
  • Cell Line, Tumor
  • Depression
  • Humans
  • Immunologic Factors
  • Immunotherapy
  • Ligands
  • Neoplasms* / drug therapy
  • Oxygen
  • Programmed Cell Death 1 Receptor* / metabolism
  • Prospective Studies

Substances

  • Albumins
  • Antibodies, Monoclonal
  • B7-H1 Antigen
  • Carbocyanines
  • Immunologic Factors
  • Ligands
  • Programmed Cell Death 1 Receptor
  • heptamethine cyanine dye
  • Oxygen