Simultaneous detection of sibutramine and phenolphthalein in a diet jelly health food product that caused health problems

Anal Sci. 2023 Apr;39(4):455-461. doi: 10.1007/s44211-022-00217-0. Epub 2022 Dec 6.

Abstract

The Public Health Center in Chiba Prefecture, Japan, received a consultation from a resident of Chiba Prefecture who consumed a diet jelly health food product and experienced health problems. To investigate the cause of the health problems, we examined the two food products for the presence of pharmaceutical ingredients. A screening analysis using ultra-high-performance liquid chromatography with a photodiode array detector (UPLC-PDA) indicated the presence of sibutramine and phenolphthalein in the food product. Analysis using an ultra-high-performance liquid chromatography-quadrupole-Kingdon trap mass spectrometer (UHPLC-Q-Kingdon trap MS) confirmed the presence of sibutramine and phenolphthalein. Quantitative analysis using UPLC-PDA showed that sibutramine and phenolphthalein were present at 15 and 16 mg/bag and 2.4 and 2.6 mg/bag, respectively. According to the drug insert for sibutramine capsules in the United States, the recommended medicinal dose of sibutramine should not exceed 15 mg/day, and the amount ingested in the present case exceeded that value. The present study results indicated that ingestion of the jelly health food product may cause health problems.

Keywords: Diet jelly; Health problem; Phenolphthalein; Sibutramine.

Publication types

  • Case Reports

MeSH terms

  • Chromatography, High Pressure Liquid / methods
  • Diet*
  • Humans
  • Mass Spectrometry / methods
  • Phenolphthalein* / analysis

Substances

  • sibutramine
  • Phenolphthalein