Matrix-assisted laser desorption/ionisation-time of flight mass spectrometry azole susceptibility assessment in Candida and Aspergillus species

Mem Inst Oswaldo Cruz. 2023 Mar 13:118:e220213. doi: 10.1590/0074-02760220213. eCollection 2023.

Abstract

Background: Matrix-assisted laser desorption/ionisation-time of flight mass spectrometry (MALDI-TOF MS) allows rapid pathogen identification and potentially can be used for antifungal susceptibility testing (AFST).

Objectives: We evaluated the performance of the MALDI-TOF MS in assessing azole susceptibility, with reduced incubation time, by comparing the results with the reference method Broth Microdilution.

Methods: Resistant and susceptible strains of Candida (n = 15) were evaluated against fluconazole and Aspergillus (n = 15) against itraconazole and voriconazole. Strains were exposed to serial dilutions of the antifungals for 15 h. Microorganisms' protein spectra against all drug concentrations were acquired and used to generate a composite correlation index (CCI) matrix. The comparison of autocorrelations and cross-correlations between spectra facilitated by CCI was used as a similarity parameter between them, enabling the inference of a minimum profile change concentration breakpoint. Results obtained with the different AFST methods were then compared.

Findings: The overall agreement between methods was 91.11%. Full agreement (100%) was reached for Aspergillus against voriconazole and Candida against fluconazole, and 73.33% of agreement was obtained for Aspergillus against itraconazole.

Main conclusions: This study demonstrates MALDI-TOF MS' potential as a reliable and faster alternative for AFST. More studies are necessary for method optimisation and standardisation for clinical routine application.

MeSH terms

  • Antifungal Agents / pharmacology
  • Aspergillus
  • Azoles / pharmacology
  • Candida*
  • Fluconazole* / pharmacology
  • Itraconazole / pharmacology
  • Lasers
  • Microbial Sensitivity Tests
  • Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization / methods
  • Voriconazole / pharmacology

Substances

  • Voriconazole
  • Fluconazole
  • Azoles
  • Itraconazole
  • Antifungal Agents