Extracellular vesicles from human plasma for biomarkers discovery: Impact of anticoagulants and isolation techniques

PLoS One. 2023 May 10;18(5):e0285440. doi: 10.1371/journal.pone.0285440. eCollection 2023.

Abstract

Extracellular vesicles (EVs) isolated from plasma are increasingly recognized as promising circulating biomarkers for disease discovery and progression, as well as for therapeutic drug delivery. The scientific community underlined the necessity of standard operative procedures for the isolation and storage of the EVs to ensure robust results. The understanding of the impact of the pre-analytical variables is still limited and some considerations about plasma anticoagulants and isolation methods are necessary. Therefore, we performed a comparison study between EVs isolated by ultracentrifugation and by affinity substrate separation from plasma EDTA and sodium citrate. The EVs were characterized by Nano Tracking Analysis, Western Blot, cytofluorimetric analysis of surface markers, and lipidomic analysis. While anticoagulants did not significantly alter any of the analyzed parameters, the isolation methods influenced EVs size, purity, surface markers expression and lipidomic profile. Compared to ultracentrifugation, affinity substrate separation yielded bigger particles highly enriched in tetraspanins (CD9, CD63, CD81), fatty acids and glycerolipids, with a predominant LDL- and vLDL-like contamination. Herein, we highlighted that the isolation method should be carefully evaluated prior to study design and the need of standardized operative procedures for EVs isolation and application to biomarkers discovery.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anticoagulants* / metabolism
  • Anticoagulants* / pharmacology
  • Biomarkers / metabolism
  • Blotting, Western
  • Extracellular Vesicles* / metabolism
  • Humans
  • Plasma / metabolism

Substances

  • Anticoagulants
  • Biomarkers

Grants and funding

This study was funded by the Università del Piemonte Orientale (FAR 2017 and FAR 2019) (DC), and by the Italian Ministry of Education, University, and Research (MIUR) program’s “Departments of Excellence 2018–2022”, AGING Project The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.