Irreversible two-photon photorearrangement of 1,2-diarylethenes is a unique process providing access to complex 2a1 ,5a-dihydro-5,6-dithiaacenaphthylene (DDA) heterocyclic core. This reaction was serendipitously discovered during studies on photoswitchable diarylethenes and was initially considered as a highly undesired process. However, in recent years, it has been recognized as an efficient photochemical reaction, interesting by itself and as a promising synthetic method for the synthesis of challenging molecules. Herein, we discuss the state-of-the-art in studies on this notable process.
Keywords: diarylethene; heterocycles; photoreaction; photorearrangement; photoswitching.
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