Decohesion of a polyolefin overlay from a substrate high density polyethylene layer by impact induced stress waves

Waste Manag. 2023 Sep 28:171:393-400. doi: 10.1016/j.wasman.2023.09.031. Online ahead of print.

Abstract

High-density polythene (HDPE) is difficult to separate from food packaging waste for recycling because the packaging occasionally has multilayer plastic labels attached. Solvents are employed in the current separation techniques to remove undesirable layers from HDPE substrates. The possibility of separating HDPE via the impact-delamination phenomenon was explored both theoretically and experimentally. Using the cohesive zone model (CZM), the decohesion of layers in a model two-layer laminate made of HDPE and LDPE layers was studied theoretically. According to this study, stress waves emerge and severely damage the adhesion between the layers as a cutting blade strikes the laminate at speeds greater than 40 m/s. The damage can be enhanced by increasing the strike velocity and the apex radius of the blade. These findings show that a novel plastic delaminator that can cut and delaminate the laminates simultaneously can be designed. The proposed machine will feature two sets of blades with varying edge apex radii. One set of blades can be designed to cause the most adhesion damage while the other blades cut the laminate. This unique combination of cutting and delamination operations has several benefits, including less solvent waste and downstream processes, greater environmental friendliness, and faster HDPE separation. Laminates from HDPE milk bottles were cut using a high-speed cutter-blender with six blades to test the predicted results. The cut HDPE flakes were separated pneumatically. According to FTIR analysis and SEM, only a trace of adhesive was present on the cut and separated HDPE flakes.

Keywords: Adhesive failure; HDPE; Impact delamination; Laminates; Recycling; Stress waves.