During synthetic textile washing, rubbing between fibres or against the washing machine, exacerbated by the elevated temperature, initiates the release of millions of microplastic fibres into the environment. A general tribological strategy is reported that practically eliminates the release of microplastic fibres from laundered apparel. The two-layer fabric finishes combine low-friction, liquidlike polymer brushes with "molecular primers", that is, molecules that durably bond the low-friction layers to the surface of the polyester or nylon fabrics. It is shown that when the coefficient of friction is below a threshold of 0.25, microplastic fibre release is substantially reduced, by up to 96%. The fabric finishes can be water-wicking or water-repellent, and their comfort properties are retained after coating, indicating a tunable and practical strategy toward a sustainable textile industry and plastic-free oceans and marine foodstuffs.
Keywords: fabric finishes; microplastic fibres; nylon‐6,6; polyester; polymer brushes; sustainable textiles.
© 2024 The Authors. Small published by Wiley‐VCH GmbH.