Essential oil from Piper tuberculatum Jacq. (Piperaceae) and its majority compound β-caryophyllene: mechanism of larvicidal action against Aedes aegypti (Diptera: Culicidae) and selective toxicity

Environ Sci Pollut Res Int. 2024 May;31(23):33454-33463. doi: 10.1007/s11356-024-33416-5. Epub 2024 Apr 29.

Abstract

Synthetic insecticides have been the primary approach in controlling Aedes aegypti; however, their indiscriminate use has led to the development of resistance and toxicity to non-target animals. In contrast, essential oils (EOs) are alternatives for vector control. This study investigated the mechanism of larvicidal action of the EO and β-caryophyllene from Piper tuberculatum against A. aegypti larvae, as well as evaluated the toxicity of both on non-target animals. The EO extracted from P. tuberculatum leaves was majority constituted of β-caryophyllene (54.8%). Both demonstrated larvicidal activity (LC50 of 48.61 and 57.20 ppm, p < 0.05), acetylcholinesterase inhibition (IC50 of 57.78 and 71.97 ppm), and an increase in the production of reactive oxygen and nitrogen species in larvae after exposure to the EO and β-caryophyllene. Furthermore, EO and β-caryophyllene demonstrate no toxicity to non-target animals Toxorhynchites haemorrhoidalis, Anisops bouvieri, and Diplonychus indicus (100% of survival rate), while the insecticide α-cypermethrin was highly toxic (100% of death). The results demonstrate that the EO from P. tuberculatum and β-caryophyllene are important larvicidal agents.

Keywords: Aedes; Piper; Caryophyllene; Ecotoxicity; Larvicidal; Oxidative.

MeSH terms

  • Aedes* / drug effects
  • Animals
  • Insecticides*
  • Larva* / drug effects
  • Oils, Volatile* / chemistry
  • Oils, Volatile* / pharmacology
  • Piper* / chemistry
  • Plant Leaves / chemistry
  • Polycyclic Sesquiterpenes*

Substances

  • Oils, Volatile
  • Insecticides
  • Polycyclic Sesquiterpenes
  • caryophyllene