High pressures studies on bis(L-alaninate)copper(II) by Raman spectroscopy and synchrotron X-ray diffraction

Abstract

The crystal of bis(L-alaninate)copper(II) [Cu(C₃H₆NO₂)₂] was studied by Raman spectroscopy and synchrotron X-ray diffraction as a function of hydrostatic pressure, and its vibrational and structural behavior were investigated to analyze its stability at high pressures. The Raman spectra of bis(L-alaninate)copper(II) show changes in vibrational modes that are associated with deformations and stretching of units involving the copper atom. These results indicate that molecular fragments involving the copper atom undergo rotations and discontinuities in bond lengths. The lattice parameters of bis(L-alaninate)copper(II) obtained from Le Bail fits also exhibit changes in the same pressure ranges as the Raman spectra. The discontinuities in the angular parameter beta are compatible with the rotations of the molecular fragments. Bis(L-alaninate)copper(II) undergoes changes, but maintains monoclinic symmetry in the range of 0-20.1 GPa.

Keywords: Bis(L-alaninate)copper(II); High pressures; Metal-complexed amino acids; Raman spectroscopy; Synchrotron radiation; X-ray diffraction.