Selective glucose electro-oxidation catalyzed by TEMPO on graphite felt

Abstract

Long-term electrolyses of glucose in a potassium carbonate (K₂CO₃) aqueous electrolyte have been performed on graphite felt electrodes with TEMPO as a homogeneous catalyst. The influences of the operating conditions (initial concentrations of glucose, TEMPO, and K₂CO₃ along with applied anode potential) on the conversion, selectivity toward gluconate/glucarate, and faradaic efficiency were assessed first. Then, optimizations of the conversion, selectivity, and faradaic efficiency were performed using design of experiments based on the L₉ (3⁴) Taguchi table, which resulted in 84% selectivity toward gluconate with 71% faradaic efficiency for up to 79% glucose conversion. Side products such as glucaric acid were also obtained when the applied potential exceeded 1.5 V vs. reversible hydrogen electrode.

Keywords: TEMPO; electro-oxidation; glucaric acid; gluconic acid; glucose; optimization.