A High-Avidity, Thermostable, and Low-Cost Synthetic Capture for Ultrasensitive Detection and Quantification of Viral Antigens and Aerosols

ACS Sens. 2024 Jun 28;9(6):3096-3104. doi: 10.1021/acssensors.4c00282. Epub 2024 May 16.

Abstract

Lateral flow assays (LFAs) are currently the most popular point-of-care diagnostics, rapidly transforming disease diagnosis from expensive doctor checkups and laboratory-based tests to potential on-the-shelf commodities. Yet, their sensitive element, a monoclonal antibody, is expensive to formulate, and their long-term storage depends on refrigeration technology that cannot be met in resource-limited areas. In this work, LCB1 affibodies (antibody mimetic miniproteins) were conjugated to bovine serum albumin (BSA) to afford a high-avidity synthetic capture (LCB1-BSA) capable of detecting the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) spike protein and virus like particles (VLPs). Substituting the monoclonal antibody 2B04 for LCB1-BSA (stable up to 60 °C) significantly improved the thermal stability, shelf life, and affordability of plasmonic-fluor-based LFAs (p-LFAs). Furthermore, this substitution significantly improved the sensitivity of p-LFAs toward the spike protein and VLPs with precise quantitative ability over 2 and 3 orders of magnitude, respectively. LCB1-BSA sensors could detect VLPs at 100-fold lower concentrations, and this improvement, combined with their robust nature, enabled us to develop an aerosol sampling technology to detect aerosolized viral particles. Synthetic captures like LCB1-BSA can increase the ultrasensitivity, availability, sustainability, and long-term accuracy of LFAs while also decreasing their manufacturing costs.

Keywords: COVID-19; lateral flow assay; novel antibody synthesis; passive sampling; point-of-care; virus like particles.

MeSH terms

  • Aerosols* / chemistry
  • Antibodies, Monoclonal / chemistry
  • Antibodies, Monoclonal / immunology
  • Antigens, Viral* / analysis
  • Antigens, Viral* / immunology
  • COVID-19 / diagnosis
  • COVID-19 / virology
  • Humans
  • Immunoassay / methods
  • Limit of Detection
  • SARS-CoV-2* / immunology
  • SARS-CoV-2* / isolation & purification
  • Serum Albumin, Bovine / chemistry
  • Spike Glycoprotein, Coronavirus* / immunology
  • Temperature

Substances

  • Aerosols
  • Spike Glycoprotein, Coronavirus
  • spike protein, SARS-CoV-2
  • Antigens, Viral
  • Serum Albumin, Bovine
  • Antibodies, Monoclonal