Recycling of Ti and Si from Ti-bearing blast furnace slag and diamond wire saw silicon waste by flux alloying technique

J Environ Manage. 2024 Jun:362:121302. doi: 10.1016/j.jenvman.2024.121302. Epub 2024 Jun 1.

Abstract

Two industrial solid wastes, Ti-bearing blast furnace slag (TBFS) and diamond wire saw silicon waste (DWSSW), contain large amounts of Ti and Si, and their accumulation wastes resources and intensifies environmental pollution. In the present study, DWSSW was used as the silicon source to reduce titanium oxide in TBFS by electromagnetic induction smelting, and meanwhile Na3AlF6 was added as a flux to improve the recycling of the wastes. Ti and Si of the two wastes were simultaneously recovered in the form of alloy. The effects of different addition amount of Na3AlF6 flux in the mixture of DWSSW and TBFS on chemical composition, viscosity, basicity and structure of slag were investigated. The dissolution behavior of SiO2 in Na3AlF6 flux was theoretically deduced and experimentally verification. The optimized recovery rate of Ti and Si were obtained, and the research realizes the efficient recycling of DWSSW and TBFS simultaneously.

Keywords: Diamond wire saw silicon waste; Electromagnetic induction; Flux alloying; Recovery rate; Ti-bearing blast furnace slag.

MeSH terms

  • Alloys* / chemistry
  • Diamond / chemistry
  • Industrial Waste / analysis
  • Recycling*
  • Silicon* / chemistry
  • Titanium* / chemistry

Substances

  • Titanium
  • Silicon
  • Alloys
  • Diamond
  • Industrial Waste