The N-terminal SAM domain of the dNTPase SAMHD1 is not required for inhibition by small molecule TH6342

Nucleosides Nucleotides Nucleic Acids. 2024;43(8):831-836. doi: 10.1080/15257770.2024.2325439. Epub 2024 Jun 3.

Abstract

Sterile alpha motif and histidine-aspartic acid domain containing protein-1 (SAMHD1) is a deoxynucleoside triphosphate (dNTP) hydrolase that controls dNTP pools and detoxifies cancer cells of chemotherapy metabolites. TH6342 is a recently reported small molecule inhibitor of SAMHD1 that interacts with the protein in vitro and non-competitively prevents dimerisation, a prerequisite for catalysis. The binding site of TH6342 on SAMHD1 is currently unknown. In the present study we demonstrate that the N-terminal SAM domain of SAMHD1 is not required for inhibition by TH6342.

Keywords: SAMHD1; TH6342; dNTP hydrolase; mode-of-inhibition; small molecule inhibitor.

MeSH terms

  • Binding Sites
  • Enzyme Inhibitors / chemistry
  • Enzyme Inhibitors / pharmacology
  • Humans
  • Protein Domains
  • SAM Domain and HD Domain-Containing Protein 1* / chemistry
  • SAM Domain and HD Domain-Containing Protein 1* / metabolism

Substances

  • SAM Domain and HD Domain-Containing Protein 1
  • SAMHD1 protein, human
  • Enzyme Inhibitors