Microsecond time-resolved X-ray scattering by utilizing MHz repetition rate at second-generation XFELs

Nat Methods. 2024 Sep;21(9):1608-1611. doi: 10.1038/s41592-024-02344-0. Epub 2024 Jul 5.

Abstract

Detecting microsecond structural perturbations in biomolecules has wide relevance in biology, chemistry and medicine. Here we show how MHz repetition rates at X-ray free-electron lasers can be used to produce microsecond time-series of protein scattering with exceptionally low noise levels of 0.001%. We demonstrate the approach by examining Jɑ helix unfolding of a light-oxygen-voltage photosensory domain. This time-resolved acquisition strategy is easy to implement and widely applicable for direct observation of structural dynamics of many biochemical processes.

MeSH terms

  • Lasers
  • Time Factors
  • X-Ray Diffraction* / methods
  • X-Rays