Exploring the Role of Neuropeptide PACAP in Cytoskeletal Function Using Spectroscopic Methods

Int J Mol Sci. 2024 Jul 24;25(15):8063. doi: 10.3390/ijms25158063.

Abstract

The behavior and presence of actin-regulating proteins are characteristic of various clinical diseases. Changes in these proteins significantly impact the cytoskeletal and regenerative processes underlying pathological changes. Pituitary adenylate cyclase-activating polypeptide (PACAP), a cytoprotective neuropeptide abundant in the nervous system and endocrine organs, plays a key role in neuron differentiation and migration by influencing actin. This study aims to elucidate the role of PACAP as an actin-regulating polypeptide, its effect on actin filament formation, and the underlying regulatory mechanisms. We examined PACAP27, PACAP38, and PACAP6-38, measuring their binding to actin monomers via fluorescence spectroscopy and steady-state anisotropy. Functional polymerization tests were used to track changes in fluorescent intensity over time. Unlike PACAP27, PACAP38 and PACAP6-38 significantly reduced the fluorescence emission of Alexa488-labeled actin monomers and increased their anisotropy, showing nearly identical dissociation equilibrium constants. PACAP27 showed weak binding to globular actin (G-actin), while PACAP38 and PACAP6-38 exhibited robust interactions. PACAP27 did not affect actin polymerization, but PACAP38 and PACAP6-38 accelerated actin incorporation kinetics. Fluorescence quenching experiments confirmed structural changes upon PACAP binding; however, all studied PACAP fragments exhibited the same effect. Our findings indicate that PACAP38 and PACAP6-38 strongly bind to G-actin and significantly influence actin polymerization. Further studies are needed to fully understand the biological significance of these interactions.

Keywords: PACAP; TBI; actin; biomarker; cytoskeletal rearrangement; fluorescence spectroscopy.

MeSH terms

  • Actin Cytoskeleton / metabolism
  • Actins* / chemistry
  • Actins* / metabolism
  • Animals
  • Cytoskeleton / metabolism
  • Humans
  • Kinetics
  • Pituitary Adenylate Cyclase-Activating Polypeptide* / chemistry
  • Pituitary Adenylate Cyclase-Activating Polypeptide* / metabolism
  • Protein Binding
  • Spectrometry, Fluorescence* / methods

Substances

  • Pituitary Adenylate Cyclase-Activating Polypeptide
  • Actins