Optimization of Filling Material Ratio in Yellow Phosphorus Slag Mine

Materials (Basel). 2024 Nov 12;17(22):5521. doi: 10.3390/ma17225521.

Abstract

Yellow phosphorus slag has been considered as a potential cement substitute for mine filling material due to its cementing activity; however, its slow setting and low early strength have limited broader use. This study investigates the grading, compactness, and strength of yellow phosphorus slag combined with tailing sand. Using yellow phosphorus slag as an aggregate, cement as a binder, and mixing tailing sand in different ratios, this study evaluates its feasibility as a coarse aggregate in mine backfill. The key findings are as follows. (1) The grading index of tailing sand was 0.5, aligning with Fuller grading, but it required mixing with coarse aggregates to enhance strength and reduce cement consumption. Yellow phosphorus slag, with a grading index of 0.97, does not match Fuller's curve and thus benefits from mixing with tailing sand. (2) For mixtures of waste rock and tailings, the 5:5 ratio aligned closely with Fuller's theory, showing optimal packing density and strength. Mixtures of yellow phosphorus slag and tailings at ratios of 3:7, 4:6, and 5:5 had R2 values of 0.73, 0.80, and 0.85, respectively, confirming reliable fit. The 5:5 mixture provided the best packing density and strength. (3) A new strength prediction model, accounting for aggregate, cement, and water effects, suggests that a 5:5 ratio with a 71% mass concentration and 1/7 ash-sand ratio meets industrial strength requirements. FLAC3D simulations indicated that cemented backfill reduces stress concentrations caused by excavation and supports stability during mining while also absorbing energy through compaction, creating favorable conditions for safe mining operations.

Keywords: filling strength; filling value calculation; mixed filling material; packing density models; yellow phosphorus slag.

Grants and funding

This research received no external funding.