Synthesis, characterization, and application potential of chitosan/acrylamide composite hydrogels as skin expanders

J Mater Sci Mater Med. 2024 Nov 30;35(1):72. doi: 10.1007/s10856-024-06812-z.

Abstract

Hydrogels are currently widely used in regenerative medicine and wound repair due to their superior biocompatibility, reliable mechanical strength, and good morphological memory. We aimed to prepare a self-expanding hydrogel that can be used as a skin expander for the repair of large soft skin tissue defects. Self-expanding hydrogels were prepared by chemical cross-linking, which consisted of water-soluble chitosan (CS), acrylamide (AM), methylene bisacrylamide (NMBA), etc. Five groups of in vitro experiments, including (CS-AM) of 0% (pure AM group), 13.9%, 27.8%, 41.7%, and 55.6%, were conducted to determine mechanical properties, swelling properties, cytotoxicity, etc. In the rat model, both a tight skin area (neck) and a loose skin area (back) were selected for expansion with hydrogels. A total of 27.8% of the CS-AM samples expanded stably under the skin of the rats, achieving 370% expansion in the tight zone and 490% expansion in the flaccid zone. Subcutaneous histopathological examination suggested that the inflammation index of the pericolloid tissue was lower in the CS-AM group than in the pure AM group. Our results demonstrate that self-expanding CS-AM hydrogels have great potential for application as skin expanders.

MeSH terms

  • Acrylamide* / chemistry
  • Animals
  • Biocompatible Materials* / chemical synthesis
  • Biocompatible Materials* / chemistry
  • Chitosan* / chemistry
  • Humans
  • Hydrogels* / chemistry
  • Male
  • Materials Testing*
  • Rats
  • Rats, Sprague-Dawley
  • Skin* / pathology
  • Tissue Expansion / methods
  • Tissue Expansion Devices
  • Wound Healing / drug effects

Substances

  • Chitosan
  • Hydrogels
  • Acrylamide
  • Biocompatible Materials