ZIF-67 nanocubes assembly-derived CoTe2 nanoparticles encapsulated hierarchical carbon nanofibers enables efficient lithium storage

Wu-Di Zhang; Xiao-Ye Ge; Kang-Kang Zhao; Qiang Zhang; Fu-Hu Cao; Xingyu Guo; Chuan-Ling Zhang

doi:10.1016/j.jcis.2024.12.040

ZIF-67 nanocubes assembly-derived CoTe₂ nanoparticles encapsulated hierarchical carbon nanofibers enables efficient lithium storage

J Colloid Interface Sci. 2024 Dec 7:682:1028-1039. doi: 10.1016/j.jcis.2024.12.040. Online ahead of print.

Authors

Wu-Di Zhang¹, Xiao-Ye Ge¹, Kang-Kang Zhao¹, Qiang Zhang¹, Fu-Hu Cao¹, Xingyu Guo², Chuan-Ling Zhang³

Affiliations

¹ Anhui Province Engineering Research Center of Flexible and Intelligent Materials, Anhui Province Key Laboratory of Value-Added Catalytic Conversion and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China.
² Key Laboratory for Computational Physical Sciences (MOE), Institute of Computational Physics, Department of Physics, Fudan University, Shanghai 200433, China. Electronic address: xguo@fudan.edu.cn.
³ Anhui Province Engineering Research Center of Flexible and Intelligent Materials, Anhui Province Key Laboratory of Value-Added Catalytic Conversion and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China. Electronic address: zhangcl@hfut.edu.cn.

PMID: 39662229
DOI: 10.1016/j.jcis.2024.12.040

Abstract

Tellurides are promising anode materials for lithium-ion batteries (LIBs) because of their high electronic conductivity and energy density. However, the slow kinetics and poor structural stability lead to decreased electrochemical performance. In this work, by utilizing the interface magnetization mechanism and assembly effect, high-performance CoTe₂ nanoparticles encapsulated hierarchical N-doped porous carbon nanofibers were rationally designed and prepared (ES-CoTe₂@NC) via facile tellurization of one-dimensional (1D) ZIF-67 nanocube assemblies. Benefiting from the synergistic effects of the unique structure and component, the ES-CoTe₂@NC anode exhibits a high reversible capacity of 1020 mAh/g at 0.1 A/g after 200 cycles, along with excellent long-term cycling stability, retaining a capacity of 780 mAh/g at 1 A g^-1 after 500 cycles. Notably, the ES-CoTe₂@NC anode retains a remarkable capacity of 502 mAh/g even after 1000 cycles at a high current density of 5 A g^-1, highlighting its exceptional cycling stability. Besides, the Full cell coupled with LiFePO₄ cathode delivers a high reversible capacity of 151.1 mAh g^-1 at 0.1 A g^-1 with stable cycling performance. The kinetics analysis reveals that the ES-CoTe₂@NC anode has high pseudocapacitive properties, high electronic conductivity, and fast Li⁺ diffusion capability. Moreover, the ex-situ characterization clarifies the conversion reaction mechanism of ES-CoTe₂@NC. This work provides a facile but effective way to construct high-performance CoTe₂-based electrodes.

Keywords: 1D ZIF-67 assembly; CoTe(2); Electrospinning; Hierarchically porous carbon fiber; Lithium storage.