The C-terminal domain of peptide deformylase is disordered and dispensable for activity

FEBS Lett. 1996 Apr 29;385(1-2):91-5. doi: 10.1016/0014-5793(96)00357-2.

Abstract

Upon trypsinolysis, the 18 C-terminal residues of Escherichia coli peptide deformylase were removed but the resulting form exhibited full activity. Moreover, a mutant fms gene encoding the first 145 out of the 168 residues of the enzyme was able to complement a fms(Ts) strain and exhibited full activity. Upon progressive truncation up to residue 139, both activity and stability decreased up to complete inactivation. Mutagenesis of residues of the 138-145 region highlights the importance of Leu-141 and Phe-142. N-Terminal deletions were also carried out. Beyond two residues off, the enzyme showed a dramatic instability. Finally, NMR and thermostability studies of the full-length enzyme and comparison to the 1-147 form strongly suggest that the dispensable residues are disordered in solution.

MeSH terms

  • Amidohydrolases*
  • Aminopeptidases / chemistry*
  • Aminopeptidases / genetics
  • Aminopeptidases / isolation & purification
  • Aminopeptidases / metabolism
  • Binding Sites
  • Enzyme Stability
  • Escherichia coli / enzymology
  • Genetic Complementation Test
  • Hot Temperature
  • Molecular Weight
  • Mutagenesis, Site-Directed
  • Peptide Fragments
  • Sequence Deletion
  • Structure-Activity Relationship
  • Trypsin
  • Zinc / analysis

Substances

  • Peptide Fragments
  • Aminopeptidases
  • Trypsin
  • Amidohydrolases
  • peptide deformylase
  • Zinc