Recoverin inhibits the phosphorylation of dark-adapted rhodopsin more than it does that of bleached rhodopsin: a possible mechanism through which rhodopsin kinase is prevented from participation in a side reaction

Biochem J. 1997 Jan 15;321 ( Pt 2)(Pt 2):551-5. doi: 10.1042/bj3210551.

Abstract

In its resting state rhodopsin kinase is present in an inactive from and is activated after interaction with light-activated rhodopsin (Rho*). The activated rhodopsin kinase then phosphorylates Rho* but is also able to catalyse the phosphorylation of dark-adapted rhodopsin. A consequence of the latter behaviour of the activated kinase is that at low levels of bleach a large number of phosphoryl groups are incorporated per mol of Rho*. Recoverin- and Ca2+-dependent inhibition of rhodopsin kinase was found to be inversely related to the extent of bleaching; the lower the fraction of rhodopsin bleached, the greater the inhibition. The IC50 of recoverin is approx. 1 microM at a 0.2% level of bleach and about 5 microM in a fully bleached sample. The inhibitory effect of recoverin was studied separately on the phosphorylation of rhodopsin and Rho*. The formation of phosphorylated rhodopsin was inhibited 4.5-fold more strongly than that of phosphorylated Rho*. These results are interpreted to suggest that one of the roles of the recoverin-dependent regulation of the activity of rhodopsin kinase is to prevent the enzyme from participating in the unwanted phosphorylation of dark-adapted rhodopsin, directing it to fulfil its 'correct' function of quenching the transduction activity of Rho*.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Calcium / pharmacology
  • Calcium-Binding Proteins / pharmacology*
  • Darkness
  • Eye Proteins*
  • G-Protein-Coupled Receptor Kinase 1
  • Hippocalcin
  • Light*
  • Lipoproteins*
  • Nerve Tissue Proteins*
  • Phosphorylation / drug effects
  • Protein Kinase Inhibitors*
  • Protein Kinases / metabolism
  • Recoverin
  • Rhodopsin / metabolism*
  • Rhodopsin / physiology
  • Rod Cell Outer Segment / metabolism
  • Signal Transduction / drug effects
  • Urea

Substances

  • Calcium-Binding Proteins
  • Eye Proteins
  • Lipoproteins
  • Nerve Tissue Proteins
  • Protein Kinase Inhibitors
  • Recoverin
  • Hippocalcin
  • Urea
  • Rhodopsin
  • Protein Kinases
  • G-Protein-Coupled Receptor Kinase 1
  • Calcium