Inhibition of phospholipase C gamma 1 by the prenylated flavonoids from Sophora flavescens

Planta Med. 1997 Jun;63(3):266-8. doi: 10.1055/s-2006-957670.

Abstract

The effect on the phospholipase C gamma 1 activity of eleven prenylated flavonoids from Sophora flavescens was investigated. These flavonoids exhibited relatively strong inhibitory activity with IC50 values ranged from 7.5 x 10(-6) M to 35 x 10(-5) M with the exception of kushenol H (4) (IC50 value; > 5.3 x 10(-4) M). The presence of C3-OH resulted in a significant diminution of activity and the configuration of C3-OH is likely to be another factor influencing the activity. In addition, hydration of the C-4"'-C-5"' double bond of the lavandulyl side chain caused complete loss of activity. These data suggest that the presence and configuration of C3-OH are related to the inhibitory activity and the lavandulyl side chain is also important for high inhibitory activity against PLC gamma 1.

Publication types

  • Letter
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Cattle
  • Cerebellum / enzymology
  • Enzyme Inhibitors / chemistry
  • Enzyme Inhibitors / isolation & purification
  • Enzyme Inhibitors / pharmacology*
  • Flavonoids / chemistry
  • Flavonoids / isolation & purification
  • Flavonoids / pharmacology*
  • Isoenzymes / antagonists & inhibitors*
  • Molecular Structure
  • Phospholipase C gamma
  • Structure-Activity Relationship
  • Type C Phospholipases / antagonists & inhibitors*

Substances

  • Enzyme Inhibitors
  • Flavonoids
  • Isoenzymes
  • Type C Phospholipases
  • Phospholipase C gamma