Purification and characterization of a glutamic-acid-specific endopeptidase from Bacillus subtilis ATCC 6051; application to the recovery of bioactive peptides from fusion proteins by sequence-specific digestion

Appl Microbiol Biotechnol. 1997 Jul;48(1):27-33. doi: 10.1007/s002530051010.

Abstract

Screening cultures of nonpathogenic microorganisms led us to a glutamic-acid-specific endopeptidase from Bacillus subtilis ATCC 6051, which we purified and named BSase. The nucleotide sequence encoding BSase, with a molecular mass of 23,894 Da, completely agreed with that of the mpr gene, which had been reported by Rufo Jr. and Sloma et al. to encode a metalloprotease [J Bacteriol (1990) 172: 1019-1023 and 1024-1029 respectively]. However, enzymatic characterization revealed it to have the catalytic triad of a serine protease and not the consensus sequence of a metalloprotease, and it was inhibited by diisopropylfluorophosphate. We therefore consider BSase (mpr) to be a serine protease. In the alignment of the acidic-amino-acid-specific proteases, the proteases from bacilli have a highly conserved histidine residue, which is most important in the histidine triad in the proteases from streptomycetes. Furthermore, Ca2+ was necessary for its activity and stability. BSase cleaved the C-terminal glutamic acid with high specificity and was very stable over a wide pH range. On the basis of these properties, we tried to retrieve a bioactive peptide from a fusion protein by sequence-specific digestion, and succeeded in obtaining the bioactive peptide. BSase was found to be very useful as a tool for selective cleavage.

Publication types

  • Comparative Study

MeSH terms

  • Amino Acid Sequence
  • Bacillus subtilis / enzymology*
  • Bacillus subtilis / genetics
  • Bacterial Proteins*
  • Cloning, Molecular
  • Glutamic Acid / metabolism*
  • Hydrogen-Ion Concentration
  • Metalloendopeptidases / genetics
  • Metalloendopeptidases / metabolism
  • Molecular Sequence Data
  • Peptide Fragments / metabolism
  • Protease Inhibitors / pharmacology
  • Recombinant Fusion Proteins / metabolism
  • Sequence Analysis
  • Sequence Homology, Amino Acid
  • Serine Endopeptidases / genetics
  • Serine Endopeptidases / isolation & purification
  • Serine Endopeptidases / metabolism*
  • Substrate Specificity

Substances

  • Bacterial Proteins
  • Peptide Fragments
  • Protease Inhibitors
  • Recombinant Fusion Proteins
  • Glutamic Acid
  • BSase protein, Bacillus subtilis
  • Serine Endopeptidases
  • Metalloendopeptidases