Proteins of newly isolated mutants and the amino-terminal proline are essential for ubiquitin-proteasome-catalyzed catabolite degradation of fructose-1,6-bisphosphatase of Saccharomyces cerevisiae

J Biol Chem. 1998 Sep 25;273(39):25000-5. doi: 10.1074/jbc.273.39.25000.

Abstract

Addition of glucose to cells of the yeast Saccharomyces cerevisiae growing on a non-fermentable carbon source leads to selective and rapid degradation of fructose-1,6-bisphosphatase. This so called catabolite inactivation of the enzyme is brought about by the ubiquitin-proteasome system. To identify additional components of the catabolite inactivation machinery, we isolated three mutant strains, gid1, gid2, and gid3, defective in glucose-induced degradation of fructose-1,6-bisphospha-tase. All mutant strains show in addition a defect in catabolite inactivation of three other gluconeogenic enzymes: cytosolic malate dehydrogenase, isocitrate lyase, and phosphoenolpyruvate carboxykinase. These findings indicate a common mechanism for the inactivation of all four enzymes. The mutants were also impaired in degradation of short-lived N-end rule substrates, which are degraded via the ubiquitin-proteasome system. Site-directed mutagenesis of the amino-terminal proline residue yielded fructose-1,6-bisphosphatase forms that were no longer degraded via the ubiquitin-proteasome pathway. All amino termini other than proline made fructose-1,6-bisphosphatase inaccessible to degradation. However, the exchange of the amino-terminal proline had no effect on the phosphorylation of the mutated enzyme. Our findings suggest an essential function of the amino-terminal proline residue for the degradation process of fructose-1,6-bisphosphatase. Phosphorylation of the enzyme was not necessary for degradation to occur.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Base Sequence
  • Biopolymers / metabolism
  • Catalysis
  • DNA Primers
  • Electrophoresis, Gel, Pulsed-Field
  • Fructose-Bisphosphatase / genetics
  • Fructose-Bisphosphatase / metabolism*
  • Hydrolysis
  • Isocitrate Lyase / antagonists & inhibitors
  • Kinetics
  • Malate Dehydrogenase / antagonists & inhibitors
  • Molecular Sequence Data
  • Mutagenesis, Site-Directed
  • Peptide Hydrolases / metabolism*
  • Phosphoenolpyruvate Carboxykinase (ATP) / antagonists & inhibitors
  • Phosphorylation
  • Polyubiquitin
  • Proline / genetics
  • Proline / metabolism*
  • Proteasome Endopeptidase Complex*
  • Saccharomyces cerevisiae / enzymology*
  • Substrate Specificity
  • Ubiquitins / metabolism

Substances

  • Biopolymers
  • DNA Primers
  • Ubiquitins
  • Polyubiquitin
  • Proline
  • Malate Dehydrogenase
  • Fructose-Bisphosphatase
  • Peptide Hydrolases
  • Proteasome Endopeptidase Complex
  • ATP dependent 26S protease
  • Phosphoenolpyruvate Carboxykinase (ATP)
  • Isocitrate Lyase