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Synthesis of 2,4-disubstituted piperidines via radical cyclization: unexpected enhancement in diastereoselectivity with tris(trimethylsilyl)silane.
J Org Chem. 2006 Jul 7;71(14):5198-207. doi: 10.1021/jo060495w.
J Org Chem. 2006.
PMID: 16808507
Tris(trimethylsilyl)silane: an unprecedented enhancement in the diastereoselectivity of radical cyclisations to give 2,4-disubstituted piperidines.
Gandon LA, Russell AG, Snaith JS.
Gandon LA, et al.
Org Biomol Chem. 2004 Aug 21;2(16):2270-1. doi: 10.1039/b409714a. Epub 2004 Jul 16.
Org Biomol Chem. 2004.
PMID: 15305204
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