Lyaskovskyy V - Search Results

1

Novel synthesis of azepine derivatives via copper-mediated cyclization of 2-aza-hepta-2,4-dien-6-ynyl anions. Intramolecular addition of organocopper centers to the C-C triple bond.

Lyaskovskyy V, Bergander K, Fröhlich R, Würthwein EU. Lyaskovskyy V, et al. Org Lett. 2007 Mar 15;9(6):1049-52. doi: 10.1021/ol063081y. Epub 2007 Feb 14. Org Lett. 2007. PMID: 17298076

2

Mechanistic study on rearrangement cascades starting from annulated 2-aza-hepta-2,4-dienyl-6-ynyl anions: formation of aniline and azepine derivatives.

Lyaskovskyy V, Fröhlich R, Würthwein EU. Lyaskovskyy V, et al. Chemistry. 2007;13(11):3113-9. doi: 10.1002/chem.200601491. Chemistry. 2007. PMID: 17205595

3

Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.

Goswami M, Lyaskovskyy V, Domingos SR, Buma WJ, Woutersen S, Troeppner O, Ivanović-Burmazović I, Lu H, Cui X, Zhang XP, Reijerse EJ, DeBeer S, van Schooneveld MM, Pfaff FF, Ray K, de Bruin B. Goswami M, et al. Among authors: lyaskovskyy v. J Am Chem Soc. 2015 Apr 29;137(16):5468-79. doi: 10.1021/jacs.5b01197. Epub 2015 Apr 16. J Am Chem Soc. 2015. PMID: 25844713 Free PMC article.

4

Mechanism of cobalt(II) porphyrin-catalyzed C-H amination with organic azides: radical nature and H-atom abstraction ability of the key cobalt(III)-nitrene intermediates.

Lyaskovskyy V, Suarez AI, Lu H, Jiang H, Zhang XP, de Bruin B. Lyaskovskyy V, et al. J Am Chem Soc. 2011 Aug 10;133(31):12264-73. doi: 10.1021/ja204800a. Epub 2011 Jul 18. J Am Chem Soc. 2011. PMID: 21711027

5

Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications.

Olivos Suarez AI, Lyaskovskyy V, Reek JN, van der Vlugt JI, de Bruin B. Olivos Suarez AI, et al. Among authors: lyaskovskyy v. Angew Chem Int Ed Engl. 2013 Nov 25;52(48):12510-29. doi: 10.1002/anie.201301487. Epub 2013 Nov 8. Angew Chem Int Ed Engl. 2013. PMID: 24214688

6

Preorganized frustrated Lewis pairs.

Bertini F, Lyaskovskyy V, Timmer BJ, de Kanter FJ, Lutz M, Ehlers AW, Slootweg JC, Lammertsma K. Bertini F, et al. Among authors: lyaskovskyy v. J Am Chem Soc. 2012 Jan 11;134(1):201-4. doi: 10.1021/ja210214r. Epub 2011 Dec 20. J Am Chem Soc. 2012. PMID: 22185581

7

Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene-cyclobutadiene rearrangement.

Lyaskovskyy V, Elders N, Ehlers AW, Lutz M, Slootweg JC, Lammertsma K. Lyaskovskyy V, et al. J Am Chem Soc. 2011 Jun 29;133(25):9704-7. doi: 10.1021/ja203083c. Epub 2011 Jun 7. J Am Chem Soc. 2011. PMID: 21627326

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