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Page 1
Sequential C-H Arylation and Enantioselective Hydrogenation Enables Ideal Asymmetric Entry to the Indenopiperidine Core of an 11β-HSD-1 Inhibitor.
Wei X, Qu B, Zeng X, Savoie J, Fandrick KR, Desrosiers JN, Tcyrulnikov S, Marsini MA, Buono FG, Li Z, Yang BS, Tang W, Haddad N, Gutierrez O, Wang J, Lee H, Ma S, Campbell S, Lorenz JC, Eckhardt M, Himmelsbach F, Peters S, Patel ND, Tan Z, Yee NK, Song JJ, Roschangar F, Kozlowski MC, Senanayake CH. Wei X, et al. Among authors: desrosiers jn. J Am Chem Soc. 2016 Nov 30;138(47):15473-15481. doi: 10.1021/jacs.6b09764. Epub 2016 Nov 17. J Am Chem Soc. 2016. PMID: 27794616 Free PMC article.
Efficient asymmetric synthesis of P-chiral phosphine oxides via properly designed and activated benzoxazaphosphinine-2-oxide agents.
Han ZS, Goyal N, Herbage MA, Sieber JD, Qu B, Xu Y, Li Z, Reeves JT, Desrosiers JN, Ma S, Grinberg N, Lee H, Mangunuru HP, Zhang Y, Krishnamurthy D, Lu BZ, Song JJ, Wang G, Senanayake CH. Han ZS, et al. Among authors: desrosiers jn. J Am Chem Soc. 2013 Feb 20;135(7):2474-7. doi: 10.1021/ja312352p. Epub 2013 Feb 6. J Am Chem Soc. 2013. PMID: 23369026
Remarkable enhancement of enantioselectivity in the asymmetric conjugate addition of dimethylzinc to (Z)-nitroalkenes with a catalytic [(MeCN)₄Cu]PF₆-Hoveyda ligand complex.
Zeng X, Gao JJ, Song JJ, Ma S, Desrosiers JN, Mulder JA, Rodriguez S, Herbage MA, Haddad N, Qu B, Fandrick KR, Grinberg N, Lee H, Wei X, Yee NK, Senanayake CH. Zeng X, et al. Among authors: desrosiers jn. Angew Chem Int Ed Engl. 2014 Nov 3;53(45):12153-7. doi: 10.1002/anie.201406247. Epub 2014 Sep 15. Angew Chem Int Ed Engl. 2014. PMID: 25225113
A mild dihydrobenzooxaphosphole oxazoline/iridium catalytic system for asymmetric hydrogenation of unfunctionalized dialins.
Qu B, Samankumara LP, Ma S, Fandrick KR, Desrosiers JN, Rodriguez S, Li Z, Haddad N, Han ZS, McKellop K, Pennino S, Grinberg N, Gonnella NC, Song JJ, Senanayake CH. Qu B, et al. Among authors: desrosiers jn. Angew Chem Int Ed Engl. 2014 Dec 22;53(52):14428-32. doi: 10.1002/anie.201408929. Epub 2014 Nov 10. Angew Chem Int Ed Engl. 2014. PMID: 25385009
Development of an asymmetric synthesis of a chiral quaternary FLAP inhibitor.
Fandrick KR, Mulder JA, Patel ND, Gao J, Konrad M, Archer E, Buono FG, Duran A, Schmid R, Daeubler J, Desrosiers JN, Zeng X, Rodriguez S, Ma S, Qu B, Li Z, Fandrick DR, Grinberg N, Lee H, Bosanac T, Takahashi H, Chen Z, Bartolozzi A, Nemoto P, Busacca CA, Song JJ, Yee NK, Mahaney PE, Senanayake CH. Fandrick KR, et al. Among authors: desrosiers jn. J Org Chem. 2015 Feb 6;80(3):1651-60. doi: 10.1021/jo502550h. Epub 2015 Jan 22. J Org Chem. 2015. PMID: 25562342
Efficient asymmetric synthesis of structurally diverse P-stereogenic phosphinamides for catalyst design.
Han ZS, Zhang L, Xu Y, Sieber JD, Marsini MA, Li Z, Reeves JT, Fandrick KR, Patel ND, Desrosiers JN, Qu B, Chen A, Rudzinski DM, Samankumara LP, Ma S, Grinberg N, Roschangar F, Yee NK, Wang G, Song JJ, Senanayake CH. Han ZS, et al. Among authors: desrosiers jn. Angew Chem Int Ed Engl. 2015 Apr 27;54(18):5474-7. doi: 10.1002/anie.201500350. Epub 2015 Mar 10. Angew Chem Int Ed Engl. 2015. PMID: 25757595
Diastereoselective Synthesis of α-Quaternary Aziridine-2-carboxylates via Aza-Corey-Chaykovsky Aziridination of N-tert-Butanesulfinyl Ketimino Esters.
Marsini MA, Reeves JT, Desrosiers JN, Herbage MA, Savoie J, Li Z, Fandrick KR, Sader CA, McKibben B, Gao DA, Cui J, Gonnella NC, Lee H, Wei X, Roschangar F, Lu BZ, Senanayake CH. Marsini MA, et al. Among authors: desrosiers jn. Org Lett. 2015 Nov 20;17(22):5614-7. doi: 10.1021/acs.orglett.5b02838. Epub 2015 Nov 11. Org Lett. 2015. PMID: 26558319
29 results