Emge TJ - Search Results

1

Catalytic Dehydrogenative C-C Coupling by a Pincer-Ligated Iridium Complex.

Wilklow-Marnell M, Li B, Zhou T, Krogh-Jespersen K, Brennessel WW, Emge TJ, Goldman AS, Jones WD. Wilklow-Marnell M, et al. Among authors: emge tj. J Am Chem Soc. 2017 Jul 5;139(26):8977-8989. doi: 10.1021/jacs.7b03433. Epub 2017 Jun 23. J Am Chem Soc. 2017. PMID: 28594178

2

Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex.

Kanzelberger M, Zhang X, Emge TJ, Goldman AS, Zhao J, Incarvito C, Hartwig JF. Kanzelberger M, et al. Among authors: emge tj. J Am Chem Soc. 2003 Nov 12;125(45):13644-5. doi: 10.1021/ja037363u. J Am Chem Soc. 2003. PMID: 14599186

3

Selective addition to iridium of aryl C-H bonds ortho to coordinating groups. Not chelation-assisted.

Zhang X, Kanzelberger M, Emge TJ, Goldman AS. Zhang X, et al. Among authors: emge tj. J Am Chem Soc. 2004 Oct 20;126(41):13192-3. doi: 10.1021/ja046476q. J Am Chem Soc. 2004. PMID: 15479051

4

Selective cleavage of the C-C bonds of aminoethyl groups, via a multistep pathway, by a pincer iridium complex.

Zhang X, Emge TJ, Ghosh R, Goldman AS. Zhang X, et al. Among authors: emge tj. J Am Chem Soc. 2005 Jun 15;127(23):8250-1. doi: 10.1021/ja051300p. J Am Chem Soc. 2005. PMID: 15941235

5

Dimerization of alkynes promoted by a pincer-ligated iridium complex. C-C reductive elimination inhibited by steric crowding.

Ghosh R, Zhang X, Achord P, Emge TJ, Krogh-Jespersen K, Goldman AS. Ghosh R, et al. Among authors: emge tj. J Am Chem Soc. 2007 Jan 31;129(4):853-66. doi: 10.1021/ja0647194. J Am Chem Soc. 2007. PMID: 17243822

6

A mixed-valence chloride-bridged (pincer)Ir(III)-(diene)Ir(I) complex.

Pelczar EM, Emge TJ, Goldman AS. Pelczar EM, et al. Among authors: emge tj. Acta Crystallogr C. 2007 Jul;63(Pt 7):m323-6. doi: 10.1107/S0108270107022378. Epub 2007 Jun 23. Acta Crystallogr C. 2007. PMID: 17609557

7

Combined experimental and computational studies on carbon-carbon reductive elimination from Bis(hydrocarbyl) complexes of (PCP)Ir.

Ghosh R, Emge TJ, Krogh-Jespersen K, Goldman AS. Ghosh R, et al. Among authors: emge tj. J Am Chem Soc. 2008 Aug 27;130(34):11317-27. doi: 10.1021/ja800434r. Epub 2008 Aug 5. J Am Chem Soc. 2008. PMID: 18680287

8

Solid-state changes in ligand-to-metal charge-transfer spectra of (NH3)5Ru(III)(2,4-dihydroxybenzoate) and (NH3)5Ru(III)(xanthine) chromophores.

Krogh-Jespersen K, Stibrany RT, John E, Westbrook JD, Emge TJ, Clarke MJ, Potenza JA, Schugar HJ. Krogh-Jespersen K, et al. Among authors: emge tj. Inorg Chem. 2008 Nov 3;47(21):9813-27. doi: 10.1021/ic800511g. Epub 2008 Oct 7. Inorg Chem. 2008. PMID: 18837549

9

Allene synthesis via C-C fragmentation: method and mechanistic insight.

Kolakowski RV, Manpadi M, Zhang Y, Emge TJ, Williams LJ. Kolakowski RV, et al. Among authors: emge tj. J Am Chem Soc. 2009 Sep 16;131(36):12910-1. doi: 10.1021/ja906189h. J Am Chem Soc. 2009. PMID: 19737015

10

Cleavage of sp3 C-O bonds via oxidative addition of C-H bonds.

Choi J, Choliy Y, Zhang X, Emge TJ, Krogh-Jespersen K, Goldman AS. Choi J, et al. Among authors: emge tj. J Am Chem Soc. 2009 Nov 4;131(43):15627-9. doi: 10.1021/ja906930u. J Am Chem Soc. 2009. PMID: 19827768

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